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uranium borohydride : ウィキペディア英語版 | uranium borohydride
| Section2 = }} Uranium borohydride U(BH4)4 is a volatile uranium complex with borohydride. This green-coloured compound is polymeric in the solid state but evaporates to a tetrahedral monomer. ==Preparation== This compound was first prepared by reacting uranium tetrafluoride with aluminium borohydride: : UF4 + 2 Al(BH4)3 → U(BH4)4 + 2 Al(BH4)F2 It may also be prepared by the solid-state reaction of uranium tetrachloride with lithium borohydride ''in vacuo'':〔 :UCl4 + 4 LiBH4 → U(BH4)4 + 4 LiCl Although U(BH4)4 is polymeric in the solid state, U(BH3CH3)4 is monomeric and hence more volatile.
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